basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. According to Wikipedia: “Conductometric titration is a type of titration in which the electrolytic conductivity of the reaction mixture is continuously. Conductometric titration theory states that the end-point of the titration process is determined by means of measuring conductivity. This theory is used for colloids.

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Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. In many cases, conductivity is linked directly to the total dissolved solids T.

High quality deionized water has a conductivity of about 5. Conductivity is traditionally determined by connecting the electrolyte in a Wheatstone bridge. Dilute solutions follow Kohlrausch’s Laws of concentration dependence and additivity of ionic contributions.

Ultra-pure water could achieve 18 megohms or more. Thus in the past, megohm-cm was used, sometimes abbreviated to “megohm”. Sometimes, conductivity is given in “microsiemens” omitting the distance term in the unit. The conversion of conductivity to the total dissolved solids depends on the chemical composition of the sample and can vary between 0. Typically, the conversion is done assuming that the solid is sodium chloride, i. The electrical conductivity of a solution of an electrolyte is measured by determining the resistance of the solution between two flat or cylindrical electrodes separated by a fixed distance.

Typical frequencies used are in the range 1—3 kHz. The dependence on the frequency is usually small, [4] but may become appreciable at very titratioj frequencies, an effect known as the Debye—Falkenhagen effect. A wide variety of instrumentation is commercially available. Tables of reference conductivities are available for many common solutions.

Conductometric Titration Theory | Bizfluent

Resistance, Ris proportional to the distance, lbetween the electrodes and is inversely proportional to the cross-sectional area of the sample, A noted S on the Figure above. Titrayion is also temperature-dependent. The specific conductance of a solution containing one electrolyte depends on the concentration of the electrolyte.

Therefore, it is convenient to divide the specific conductance by concentration. Strong electrolytes are hypothesized to dissociate completely in solution. The conductivity of a solution of a strong tutration at low concentration follows Kohlrausch’s Law.

Limiting here means “at the limit of the infinite dilution”. In effect, the observed conductivity of a strong electrolyte becomes directly proportional to concentration, at sufficiently low concentrations i.


As the concentration is increased however, the conductivity no longer rises in proportion. Moreover, Kohlrausch also found that the limiting conductivity of an electrolyte. It is very successful for solutions at low concentration. A weak electrolyte is one that is never fully dissociated i. In this case there is no limit of dilution below which the relationship between conductivity and concentration becomes linear.

Instead, the solution becomes ever more fully dissociated at weaker concentrations, and for low concentrations of “well behaved” weak electrolytes, the degree of dissociation of the weak electrolyte becomes proportional to the inverse square root of the concentration.

Typical weak electrolytes are weak acids and weak bases. The concentration of ions in a solution of a weak electrolyte is less than the concentration of the electrolyte itself. For acids and bases the concentrations can be calculated when the value s of the acid dissociation constant s is are known. For a monoprotic acidHA, obeying the inverse square root law, with a dissociation constant K aan explicit expression for the conductivity as a function of concentration, cknown as Ostwald’s dilution lawcan be obtained.

The reason for this is that as concentration increases the average distance between cation and anion decreases, so that there is more inter-ionic interaction. Whether this constitutes ion association is a moot point. However, it has often been assumed that cation and anion interact to form an ion pair. Thus the electrolyte is treated as if it were like a weak acid and a constant, Kcan be derived for the equilibrium.

Davies describes the results of such calculations in great detail, but states that K should not necessarily be thought of as a true equilibrium constantrather, the inclusion of an “ion-association” term is useful in extending the range of good agreement between theory and experimental conductivity data. The existence of a so-called conductance minimum in solvents having the relative permittivity under 60 has proved to be a controversial subject as regards interpretation.

Fuoss and Kraus suggested that it is caused by the formation of ion triplets, [13] and this suggestion has received some support recently. Other developments on this topic have been done by T. Shedlovsky [16]E. Pitts [17]R. Fuoss [18]Fuoss and Shedlovsky [19]Fuoss and Onsager [20].

The limiting equivalent conductivity of solutions based on mixed solvents like water alcohol has minima depending on the nature of alcohol.


Generally the conductivity of a solution increases with temperature, as the mobility of the ions increases. So called ‘compensated’ measurements are made at a convenient temperature but the value reported is a calculated value of the expected value of conductivity of the solution, as if it had been measured at the reference temperature.


This value is broadly applicable for aikipedia salts at room temperature.

Determination of the precise temperature coefficient for a specific solution is simple and instruments are typically capable of applying the derived coefficient i. The change in conductivity due to the isotope effect for deuterated electrolytes is sizable.

Notwithstanding the difficulty of theoretical interpretation, measured conductivity is a good indicator of the presence or absence of conductive ions in solution, and measurements are used extensively in many industries. This type of measurement is not ion-specific; it can sometimes be used to determine the amount of total dissolved solids T.

Sometimes, conductivity measurements are linked with other methods to increase the sensitivity of detection of specific types of ions. For example, in the boiler water technology, the boiler blowdown is continuously monitored for “cation conductivity”, which is the conductivity of the water after it has been passed through a cation exchange resin.

This is a sensitive method of monitoring anion impurities in the boiler water in the presence of excess cations those of the alkalizing agent usually used for water treatment. Beyond cation conductivity, there are analytical instruments designed to measure Degas conductivitywhere conductivity is measured after dissolved carbon dioxide has been removed from the sample, either through reboiling or dynamic degassing.

Conductivity detectors are commonly used with ion chromatography. From Wikipedia, the free encyclopedia. Environmental Instrumentation and Analysis Handbook. Retrieved 10 May Retrieved 5 January Instrumentation Reference Book 3rd. Archived from the original PDF on 7 September Retrieved 12 Conductomeetric Textbook of Physical Chemistry.

An Introduction to Aqueous Electrolyte Solutions.

Conductivity (electrolytic) – Wikipedia

Thermodynamic Properties of Very Wiiipedia Electrolytes”. Temperature Dependence and Solvent Isotope Effects”. Journal of the American Chemical Society. Aquarius Technologies Pty Ltd. Archived from the original PDF on 12 September Retrieved 17 May Retrieved from ” https: Use dmy dates from January All articles with unsourced statements Articles with unsourced statements from December Commons category link is on Wikidata Commons category link is on Wikidata using P Wikipedia articles with GND identifiers.

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